Biodiesel obtained from renewable feedstocks, such vegetable oil or animal fats, for use in compression ignition engines, is the mono-alkyl esters of long chain fatty acids (Barnwal and Sharma 2005). Biodiesel is considered as representative as possible of diesel fuel often consists of methyl esters of fatty acids that can be made from triglycerides in vegetable oils by transesterification with methanol. Biodiesel that occurs rather resembles conventional diesel fuel in its main characteristics. The advantages of the oils are that the raw materials used in production, it is natural and renewable. These types of oils derived from vegetable or animal, making it biodegradable and non-toxic. (Marchetti et al. 2007).
The plant oils usually contain
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Moisture and effect of free fatty acid
Moisture and free fatty acid is an important parameter in defining the viability of the transesterification process of vegetable oils. To perform the catalytic reaction to completion; is free fatty acid (FFA) less than 3% is needed. The higher acidity of the oil is smaller than the conversion efficiency. Either excess, as well as an inadequate amount of catalyst, may cause the formation of soap.
The starting materials are used for the base-catalyzed alcoholysis should respond certain requirements. The triglyceride should reduce the acid value and the materials ought to be significantly anhydrous. Apart from more sodium hydroxide catalysts compensate for higher acidity. But the soap that occurs due to the increase in the viscosity or the formation of a gel interference in response as well as the separation of glycerol. When the reaction conditions do not satisfy the requirements above, ester yield is significantly reduced. Methoxide and hydroxide of sodium or potassium should be preserved in a state that no water. Prolonged exposed to the air will reduce the efficiency of these catalysts through interaction with moisture and carbon
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600C and yield of approximately 80% were observed after 1 minute for soy and sunflower oil. After 1 h the conversion was nearly identical for all four oil (93 98%) (Maher, Vidya Sagar et al. 2006). The result of reaction time is to study the transesterification of beef tallow with methanol. The reaction is very slow at the first minute because of mixing and dispersion of methanol into beef tallow, from one to five minutes, the reaction proceeds very rapidly. Production of Beef Tallow methyl ester reached the highest value about 15 minutes. (Ma and Hanna
Some oils are engineered or extended with the use of synthetic chemicals. For instance, much of the lavender sold in the U.S. is the hybrid called lavandin. It is cut with synthetic linalyl acetate to improve the fragrance, then propylene glycol, DEP or DOP are added and it is sold in stores as lavender oil. In France, production of true lavender oil dropped from 87 tons in 1967 to only 12 tons in 1998. During this same period, global demand for lavender oil grew over 100%.
There are three main types of ester hydrolysis reactions: base-facilitated hydrolysis (saponification), acid-catalyzed hydrolysis (with the reverse reaction the Fischer Esterification), and enzymatic hydrolysis, triggered by lipases. Base-facilitated hydrolysis generally uses aqueous NaOH as a reagent, providing the base that attacks the carbonyl and begins the hydrolysis. Saponification hydrolyzes esters into carboxylic acids or fatty acids and alcohols. This has been used for thousands of years to produce soap from fatty acids as the salts produced from saponification can dissolve fats, surrounding them with micelles and allowing them to be easily removed with water1. It can also be used to produce glycerol from triglycerides.
The hydration of an alkene leads to the formation of an alcohol as a result of the acid-catalyzed addition of water to the double bond. This reaction mechanism is an equilibrium reaction as the forward reaction is the hydration of the alkene, and the reverse reaction is the dehydration of the alkene. Whether the equilibrium will favor the forward or reverse reaction is dependent on the conditions of the reaction. Excess water will drive the equilibrium forward as the double bond undergoes hydration. Conversely, removal of water will drive the equilibrium in the reverse direction as the alcohol undergoes dehydration.
The reaction to synthesize benzocaine was known as a Fisher esterification reaction. The Fisher esterification was reaction between alcohol and carboxylic acid in the presence of acid. The reaction was used to form an ester. In the experiment, sulfuric acid acted as a catalyst and necessary for this reaction to occur. There was a change between the –OH group of carboxylic acid to an –OCH2CH3 group in the reaction.
Abstract – Methyl trans-cinnamate is an ester that contributes to the aroma of strawberry. It can be synthesized by an acid-catalyzed Fischer esterification of a methanol and trans-cinnamic acid under reflux. The solution was extracted to obtain the organic product, and evaporated residual solvent The yield was 68%, but there is some conflicting data regarding the purity. The melting point, IR, GC-MS indicate a highly pure desired product whereas 1H NMR shows there are unreacted reagents still present.
If the sample to be analyzed is non-volatile, the techniques of derivatization or pyrolysis GC can be utilized. Gas chromatography (GC) has been an indispensable analytical technique in the application of fatty acid determinations in oilseed plant breeding, biosynthesis, and human metabolism. As well as the characterization of complex mixtures of geometric isomers when combined with other chromatographic separations and spectroscopic identification. Plant cultivators utilize GC as a more accurate and fast method to evaluate the differences and inheritance of fatty acids in oilseed crops such as rapeseed. flaxseed, and safflower.
Industries that utilize ester compounds are the perfume industry and the flavoring industry for the smells that we smell while we wear perfume and eat things, respectively. Also glass industries use polyesters (like polymethyl acrylate, etcetera) to make glass. In the process of synthesizing an ester, it is important to include a strong acid. The concentrated acid in this experiment was sulfuric acid.
Oleic destructive has been associated with reduced aggravation and been appeared to effectsly influence qualities associated with ailment . The fats in avocado are moreover completely impenetrable to warm influenced oxidation, making avocado oil a sound and safe choice for
Bio-diesel production yields undesirable by-products for example methanol and glycerin. These by-products are removed so that the bio-diesel is suitable for use. Fractional distillation is used in the essential oil, flavor and fragrance industry. Raw essential oils are extracted from different plants such as mint, clove and tee tree for example. These raw oils contains impurities that have a bad flavour or odor.
Experiment 10: Fischer Esterification Discussion In this experiment, a Fischer esterification reaction was performed in order to create methyl benzoate from benzoic acid and methanol. Then, a GC was performed to confirm that methyl benzoate had indeed been formed. An ester is an often sweet smelling organic compound which contains a carbonyl carbon bonded to an oxygen connected to another hydrocarbon. Esterification is the process by which esters are synthesized from an alcohol and a carboxylic acid.
Polyunsaturated fatty acids are well known for its protective effect on human health. However, they contain multiple double bonds which are susceptible to lipid oxidation. These have been long recognized and it is the major challenge in oil industry. Lipid oxidation is the main factor of food deterioration. It not only affects fatty acid composition and the nutritional quality of the food, it also causes undesirable changes in colour, aroma and produce toxic compounds (Wasowicz, 2004).