Inorganic industrial wastewater is produced mainly in the coal and steel industry, in the non-metallic minerals industry, and in commercial enterprises and industries for the surface processing of metals (iron picking works and electroplating plants). These wastewaters contain a large proportion of suspended matter, which can be eliminated by [6]. Sedimentation, often together with chemical flocculation through the addition of iron or aluminium salts, flocculation agents and some kinds of organic polymers [6, 7]. The purification of warm and dust-laden waste gases from blast furnaces, converters, cupola furnaces, refuse and sludge incineration plants, and aluminium works results in wastewater containing mineral and inorganic substances in dissolved …show more content…
Although it may contain some hazardous substances, such as heavy metals, it has been showing good adsorption qualities for phenolic compounds. The maximum phenol adsorption capacity has been found to be 27.9 mg/g for fly ash and 108.0 mg/g for granular activated carbon at initial phenol concentration of 100 mg/L [8] . Wang et al. [8] used fly ash as adsorbent for the removal of methylene blue from aqueous solution reporting an adsorption capacity of 4.47 mg/g. The effect [8]. of physical (heat) and chemical treatment was also studied on as-received fly ash. The heat treatment was reported to have adverse effect on the adsorption capacity of fly ash but acid treatment (by nitric acid) resulted in an increase of adsorption capacity of fly ash (7.99 mg/g) [9] Bhatnagar and Jain [9] investigated steel and fertilizer industries wastes, as an adsorbent for the adsorption of cationic dyes. …show more content…
It has been shown that biochar has good adsorption effect on typical pollutants of livestock wastewater such as organic pollutants heavy metals ,nitrogen, and phosphorus .After magnetization, biochar with good magnetic is easily separated from liquid , which is more suitable for livestock wastewater, compared to commercial activated carbon products. At the same time, because biochar has good adsorption capacity for nitrogen and phosphorus, it can be used as a slow-release fertilizer and has the characteristics of agricultural
For this lab, zeolite and magnetized zeolite were synthesized and compared with charcoal to find out with would be the most effective in the sequestering of Procion Red dye. Finding the concentration and absorbance of each zeolite, magnetized zeolite, and charcoal, along with a calibration curve, the best adsorbent is determined. Charcoal was the overall best sequestration of the Procion Red dye, since the adsorbent was highest compared to the others. Introduction Pollution has increased in the environment over the years, so the purpose of this experiment is to find the best adsorbent of chemicals to reduce the pollution.
The technique heterogeneous photocatalysis belonging to advanced oxidation process have proved to be one of the most effective treatment methods for the removal of pollutants from wastewater. In this process strong oxidizing agent hydroxyl radicals are produced which oxidizes a wide variety of organic pollutants into innocuous end products such as carbon dioxide, water and mineral acids………
In Richard Muller’s essay on Chemical Waste in America, he points out many different problems in todays disposal techniques of nuclear waste. He brings in readers by appealing to American citizens with his visual texts, guilt, and how we must start feeling some empathy for our future generations and find a solution to prevent a massive chemical waste epidemic. Mullers argument bases off his visual texts, by showing us a reality that is going on today. Among the visual texts, Muller explains the exact quantity of chemical wastes in the United States by telling his audience that, “we have already generated more than enough nuclear waste to fill up Yucca Mountain,” which is a storage bunker for chemical waste products. Muller even includes a picture of Yucca Mountain so the audience can get a feel for the absurd amount of waste we have built up.
Because we produce so much wastewater, wastewater treatment plants were built to clean wastewater faster. Wastewater goes through several stages of cleaning. The first step to cleaning wastewater is filtering out trash like rags and sticks. These trashes are moved to the landfills. Next, the wastewater flows through a grit chamber where sand and other heavy stuff sinks to the bottom.
Arsenate can replace inorganic phosphate in step 6 of glycolysis that produces 1,3-bisphosphoglycerate instead of glyceraldehyde 3-phospahte. This yields 1-arseno-3-phosphoglycerate instead, which is unstable and quickly hydrolyzes, forming the next intermediate in the pathway, 3-phosphoglycerate. This is the same product that is normally formed in step 7. This is a problem because the product forms before it should and therefore does not reach the enzyme so the energy released cannot be harvested to generated ATP. Arsenate wastes energy by the uncoupling phosphotransfer reaction so its very POISONOUS.
Several adsorbent are qualified for this purpose. Activated carbon is the most popular adsorbent which used for water softening but it cost remains its main drawback [22]. A large number of low-cost adsorbents have been utilized for ions removal [23]. Recently, natural clay minerals (e.g. bentonite) [24, 25] and zeolite [21, 26] have been widely used as adsorbents for adsorption of ionic and molecular species from various water streams.
The fly ash particles possess the fineness at the range of 1micron to 1mm size measured by Blaine’s specific area technique. Dry and wet sieving is an alternative measure for particle area. The specific gravity
Adsorption is one of the major process used for the removal of Cr(VI) worldwide because it is inexpensive, widely applicable, efficient and creates little amount of sludge(Kannan and Rengasamy, 2005). Chromium can be removed using adsorbents of natural as well as chemical origin. However, these bio-adsorbents have various disadvantages like waste may itself contain various toxicants and subsequently increase the organic content of water. Studies have showed adsorption capacities and applicability for some low-cost materials, among others like alluminium oxide, chitosan, bentonite, saw dust and waste slurry (Dubey and Gopal, 2007). Activated carbon is an effective inexpensive adsorbent which has use in various industries to purify water (D Mohan and Chander, 2001;
The residual biomass was separated by filtration and washed with distilled water. For alginate extraction, the acidified algal biomass was suspended in 3% Na2CO3 solution at different alkali: alga ratio (20, 40, and 60 mL/g). The different extraction temperatures ranged from 25 to 45º C, and lasted for 1 to 3 h. For each experimental run, sodium alginate was collected by filtration and precipitated with absolute ethanol (1:2 v/v). The mixture was maintained at 4º C overnight. The precipitate was collected by vacuum filtration and allowed to dry at room temperature.
Corresponding Author: abrar.muslim@che.unsyiah.ac.id Abstract The Australian Pine cones (APCs) was utilised as adsorbent material by physical and chemical activation for the adsorption Cu(II) from aqueous solution. FTIR and SEM analysis were conducted to obtain the active site and to characterise the surface morphology of the APCs activated carbon (APCs AC) prepared through pyrolysis at 1073.15 K and the alkaline activation of NaOH. The independent variables effect such as contact time, Cu(II) initial concentration and the activator ratio in the ranges of 0-150 mins, 6.5-370.5 mg/l and 0.2-0.6 (NaOH:APCs AC), respectively on the Cu(II) adsorption capacity were investigated in the APCs activated carbon-solution (APCs ACS) system with 1 g the APCs AC in 100 ml Cu(II) aqueous solution with magnetic stirring at 75 rpm, room temperature of 298.15 K (± 2 K), at 1 atm and normal pH. As a result, Cu(II) adsorption capacity dramatically increased with
Even though the sample with 5 mL of NaOH added appeared to be the clearest of the non-control samples, it was clear because less copper had precipitated out of suspension. Discussion and Conclusion From the experiment, it was seen that an increase in pH caused a greater Cu2+ precipitation. The precipitation process creates solids from compounds that were once dissolved in solution, and these solids must be removed by filtration or sedimentation (Casiday et al 2008). However, this was the only variable that was tested. In order to increase the efficiency of the waste removal, mixing speeds and times, as well as resting times may be varied to reduce process time and efficiency.
Con Decon Process[4] : It is a dilute chemical decontamination process that avoids the draining or flushing of the system to be decontaminated. It is also not necessary to defuel the reactor due to decontamination process. This is thus a simplified process which results in cleaning of the fuel at the same time, adding a huge advantage of removing a significant amount of activated corrosion product which if allowed to remain would eventually dissolve and redeposit out-core, thus partially negating the effects of the decontamination.
The initial phenol concentration provides an important driving force to overcome all mass transfer limitations of phenol between the aqueous and sorbent phases. Therefore a higher opening phenol concentration will enrich the biosorption process. The increase in sorption capacity of bacterial strain with an increase in the initial phenol concentration might be due to a higher probability of collision between the phenol molecules and biosorbent. With increase in phenol concentration from 100 to 500 mg/L, the percentage removal reached 99% in 2 days. The equilibrium
Many of these technologies can be applied for the removal of hexavalent chromium [1]: 1. Ex situ treatment technologies for water mostly use chemical reduction of Cr(VI) to Cr(III) followed by precipitation. 2. In situ treatment approaches often use chemical reduction and fixation for remedia- tion. Newer technologies include enhanced extraction, electrokinetics, phytoremedi- ation and natural attenuation.
Water is the most important component found on the surface of the earth because it is source of life for living creatures. However, water pollution has become a global concern. Water pollution can have several forms from diverse sources. It is expected that there will be a lack of clean water in next few decades due to pollution. Nile river water in Egypt is the focus of attention of many studies due to many reasons.