EXPERIMENTAL
Mass transfer tests
The mass transfer tests in the test reactor (2 L Büchi autoclave) where conducted using an indirect (chemical) method. The experimental procedure (detailed in Section 6.1.3) consisted of filling the reactor with approximately 1.2 mol/L sodium sulfite solution containing 1-5 mg/L cobalt(II) ion, turning on the oxygen supply and starting the time. The oxidation reaction was allowed to continue for a predetermined time agitation was started and samples taken at regular time intervals. Each sample was mixed with excess standard iodine solution and titrated with standard sodium thiosulfate solution (Na2S2O3) using a starch indicator. The reactions are (Jeffrey et al., 1989): 〖"SO" 〗_"3" ^"2-" "+ " "I" _"2" "+ " "H" _"2" "O → " 〖"SO" 〗_"4" ^"2-" "+ " 〖"2H" 〗^"+" "+ " 〖"2I" 〗^"-" 6.1
〖"2S" 〗_"2" "O" _"3" ^"2-" "+ " "I" _"2" "→ " "S" _"4" "O" _"6" ^"2-" "+ " 〖"2I" 〗^"-" 6.2
The residual amount of sulphate was determined by the stoichiometry of the reaction 6.2. Detailed solution preparation and experimental procedure is given in Appendix III.
Reagents
All solutions where prepared with deionized water and grade A chemicals.
…show more content…
Figure 6 1 presents a schematic diagram for the reactor while Figure 6 2 represents a picture of the experimental setup. The reactor is equipped with a stirrer drive with integrated high torque magnetic coupling to provide agitation. The agitation speeds were manually set and maintained throughout the course of experimentation. The reactor has an anchor type blade stirrer which was used for slurry agitation in all the tests conducted in this investigation. The pressure inside the reactor was monitored using a fitted pressure gauge. In order to obtain the desired pressure in the reactor vessel, the pressure of oxygen gas added to the reactor vessel was regulated by the pressure regulating valve fitted to the oxygen
For this lab, zeolite and magnetized zeolite were synthesized and compared with charcoal to find out with would be the most effective in the sequestering of Procion Red dye. Finding the concentration and absorbance of each zeolite, magnetized zeolite, and charcoal, along with a calibration curve, the best adsorbent is determined. Charcoal was the overall best sequestration of the Procion Red dye, since the adsorbent was highest compared to the others. Introduction Pollution has increased in the environment over the years, so the purpose of this experiment is to find the best adsorbent of chemicals to reduce the pollution.
For this I needed to first obtain deionized water. I cleaned my large graduated cylinder and got 20 + or - 2 mL of deionized water. I then added this water to the beaker that contained the mixture I created from the last step of the experiment. I also gathered 2 boiling stones and added them to the mixture of the last step. I placed the beaker on a hot plate and heated it up to 130 degrees Celsius.
Tyler White CHEM151LL 32658 04/01/2018 Different Types Chemical Reaction Types and Equations Purpose: The purpose of this lab experiment is to examine different types of chemical reactions such as Decomposition reaction, Synthesis reactions, Combustion reactions, and different Chemical equations. The experiments were conducted online using Late Nite Labs. Materials: Because the experiments were conducted online there wasn’t any physical use of materials, only digital ones, for these labs to be performed. Only the registration for the website was needed to perform these online labs, as well as a desktop computer.
The setup for the cation exchange chromatography is shown in Figure 3. This was done by plugging the bottom of a burette with a small amount of glass wool. The wool was lightly packed using a thermometer. Approximately 5 mL of Dowex 50 cation exchange resin was obtained in a small beaker, and the resin was mixed with 5 mL of pH 3 citrate buffer. This mixture was poured into the burette with the stopcock closed.
Organic Chemistry Laboratory Manual, 7th Edition, Eiley, New York, pp 96-99 Dehydration Notes
A: The compound that is being oxidized in the luminol synthesis reaction is Na2S2O4, (Sodium Hydrosulfite. Since sodium hydrosulfite is acting as the reducing agent, in this experiment. 2. What is the purpose of acetic acid in the luminol synthesis reaction? How would the amount of the luminol product obtained at the end of the reaction be affected if the number of moles of NaOH added at the beginning of the reaction and the acetic acid added at the end of the reaction added were reversed?
Many and varied are the interpretations dealing with the teachings and the life of Jesus of Nazareth. But few of these interpretations deal with what the teachings and the life of Jesus have to say to those who stand, at a moment in human history, with their backs against the wall (Thurman, 1949). Jesus was a Jew, meaning he was born visually, culturally, religiously, and ethnically different. Most of world history is man subjugating or discriminating based on appearance (Chapter 1 of “Jesus & The Disinherited”:
+ H2O (g) Reaction 4: when a sulphuric acid is added to the solution that contains copper (II) oxide, a double displacement reaction will occur. the copper (II) oxide will react with the sulphuric acid producing copper (II) sulfate and water. The copper and hydrogen gas replace each other. Balanced Chemical Equation: CuO (s) + H2SO4 (aq) —> CuSO4 (aq) + H2O (l) Reaction 5: when zinc is added to the copper (II) sulfate solution, a single displacement reaction will occur.
The temperature of the sulphuric acid was not measured throughout the experiment, however the room in which the experiment was conducted was kept constant, so the chance of any large error due to unknown temperature of the sulphuric acid was most likely reduced. The amount of sulphuric acid used was also controlled by measuring 100mL with a 100mL measuring cylinder to ensure that the results would be consistent. The volume of the agar cubes was calculated from the surface area of each agar cube, both before and after they had been in the sulphuric acid. This increased the reliability of the results as it allowed the rate of diffusion of the sulphuric acid into the agar cubes to be calculated more accurately. The concentration of the acid was 0.1M, which was placed in all three agar cubes to maintain consistency of results.
Experiment 2 Report Scaffold (Substitution Reactions, Purification, and Identification) Purpose/Introduction 1. A Sn2 reaction was conducted; this involved benzyl bromide, sodium hydroxide, an unknown compound and ethanol through reflux technique, mel-temp recordings, recrystallization, and analysis of TLC plates. 2. There was one unknown compound in the reaction that was later discovered after a series of techniques described above.
Verna Wang Hannah Palmer CHEM 101-069 Lab 11-19-16 Stoichiometry and Limiting Reagents Lab Report Purpose: We are using the reaction of sodium hydroxide and calcium chloride to illustrate stoichiometry by demonstrating proportions needed to cause a reaction to take place. Background: Just like a recipe would call for a specific amount of one ingredient to a specific amount of another, stoichiometry is the same exact method for calculating moles in a chemical reaction. Sometimes, we may not have enough of or too much of one ingredient , which would be defined as limiting and excess reagent, respectively.
Immediately 10 μL of double distilled water was added with a micropipette; this way our concentration of the treatment was the intended concentration.
Aim: To find out the relationship between the greater concentration of sodium thiosulfate when mixed with hydrochloric acid and the time it takes for the reaction (the time it takes for the solution to turn cloudy) to take place and to show the effect on the rate of reaction when the concentration of one of the reactants change. Introduction: The theory of this experiment is that sodium thiosulfate and hydrochloric acid reach together to produce sulfur as one of its products. Sulfur is a yellow precipitate so, the solution will turn to yellow color while the reaction is occurring and it will continue until it will slowly turn completely opaque. The reaction of the experiment happens with this formula: “Na2 S2 O3 + HCL =
The chemical equation for this experiment is hydrochloric acid + sodium thiosulphate + deionised water (ranging from 25ml to 0ml in 5ml intervals) sodium chloride + deionised water (ranging from 25ml to 0ml in 5ml intervals) + sulphur dioxide + sulphur. As a scientific equation, this would be written out as, NA2S2O3 + 2HCL + H2O (ranging from 25ml to 0ml in
II. METHODOLOGY In order to perform this experiment, the students will need a distillation set-up with a connector receiver, an iron ring and stand, a Bunsen burner, a wire gauze, a 250mL round bottom flask, a graduated cylinder, a thermometer, one or two boiling chips, an alcoholic beverage, masking tape, an ice bath, a stirring rod, and, optionally, food coloring. It is imporatnt to avoid playing with the apparatus and equipment so as to avoid breakage and injuries, especially since fire is being dealt with in this experiment.