Preparation Test Lab Report

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2.0 Materials and Methods
2.1 Sample preparation
Experiments are conducted on aluminum alloy with nominal composition of Si 0.4, Fe 0.5, Cu 2.0, Mn 0.3, Mg 2.9, Cr 0.28, Zn 6.1, Ti 0.2 and Al balance in wt%. Cylindrical specimens with 24 mm diameter and 5 mm thickness were used for the ENi-B deposition. Aluminum and its alloy exposed to air are always covered by a dense oxide coating that must be removed before the parts are to be plated; therefore to enhance adhesion proper pretreatment is obligatory. Sample preparation for coatings was as follows: (a) mechanically polished with wet 400, 600, 800 and 1000 grit SiC paper, (b) cleaning with acetone followed by a methanol wash, (c) acid pickling for 2min (10% HNO3 + 3% HF by volume), the samples …show more content…

Fig.8 Average roughness value (Ra) for ENi-B coatings : A without surfactant; B with SDS; C with CTAB; D with Zwitterionic 0.1M; E with Zwitterionic 0.2M; F with Zwitterionic 0.3M; G with Zwitterionic 0.4M
3.5 Corrosion characteristics
The corrosion resistance of the bare, ENi-B coatings without surfactant and with zwitterionic surfactant was investigated by potentiodynamic polarisation tests in 3.5 wt% NaCl (shown in Figure 9). The corrosion parameters (see Table 4) indicate that the ENi-B coatings without surfactant assured excellent protection of aluminum alloy against corrosion. This is due to the fact that surfactant itself is an electrolyte, in addition to the ions in the aqueous solution, which produce a galvanic (Bimetallic) corrosion which is observed by means of the oxidation potential of the respective metals. In the current case aluminum and nickel are fused together and to be suspended in the surfactant to make one metal as the anode and the other a cathode. Due to cathodic protection, the anode probably aluminum may get corroded which is read as a sacrificial anode to protect the nickel

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